In which we learn of the history of graphite, its molecular structure, and electrical properties. Then we discuss the isolation of thinner and thinner layers of graphite through the mid-to-late 20th century. The first isolation of a single atomic layer of graphite, called graphene, was accomplished in 2004 by Andre Geim and Konstantin Novoselov, which set off a new flurry of chemical research, much like the discovery of buckminsterfullerene two decades earlier. Then we discuss the special properties of graphene, and what practical applications graphene has.